Water-soluble BDPA radicals with improved persistence

Sucharita Mandal; Snorri Th Sigurdsson

doi:10.1039/d0cc04920d

Water-soluble BDPA radicals with improved persistence

Sucharita Mandal, Snorri Th Sigurdsson^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble in polar solvents and are highly persistent, with 5-20-fold lower initial rates of degradation than BDPA. This journal is

Original language	English
Pages (from-to)	13121-13124
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	86
DOIs	https://doi.org/10.1039/d0cc04920d
Publication status	Published - 7 Nov 2020

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry.

Access to Document

10.1039/d0cc04920d

Cite this

@article{8146efea2b6f4a7aaeca6f254fcb6a99,

title = "Water-soluble BDPA radicals with improved persistence",

abstract = "1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble in polar solvents and are highly persistent, with 5-20-fold lower initial rates of degradation than BDPA. This journal is ",

author = "Sucharita Mandal and Sigurdsson, {Snorri Th}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = nov,

day = "7",

doi = "10.1039/d0cc04920d",

language = "English",

volume = "56",

pages = "13121--13124",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "86",

}

TY - JOUR

T1 - Water-soluble BDPA radicals with improved persistence

AU - Mandal, Sucharita

AU - Sigurdsson, Snorri Th

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/11/7

Y1 - 2020/11/7

N2 - 1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble in polar solvents and are highly persistent, with 5-20-fold lower initial rates of degradation than BDPA. This journal is

AB - 1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble in polar solvents and are highly persistent, with 5-20-fold lower initial rates of degradation than BDPA. This journal is

UR - http://www.scopus.com/inward/record.url?scp=85094982575&partnerID=8YFLogxK

U2 - 10.1039/d0cc04920d

DO - 10.1039/d0cc04920d

M3 - Article

C2 - 33002098

AN - SCOPUS:85094982575

SN - 1359-7345

VL - 56

SP - 13121

EP - 13124

JO - Chemical Communications

JF - Chemical Communications

IS - 86

ER -

Water-soluble BDPA radicals with improved persistence

Abstract

Bibliographical note

Access to Document

Fingerprint

Cite this