Three-photon absorption spectroscopy: (3+1)REMPI of HCl (I1Δ2-X1∑+)

H. Wang; A. Kvaran

doi:10.1016/S0022-2860(00)00880-2

Three-photon absorption spectroscopy: (3+1)REMPI of HCl (I¹Δ₂-X¹∑⁺)

H. Wang, A. Kvaran^*

^*Corresponding author for this work

Faculty of Physical Sciences

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Improved spectroscopic parameters for the I¹Δ₂ Rydberg state and rotational population in the ground state of HCl are derived from simulation analysis of the (3+1)REMPI specrum. The superiority of using the (3+1)REMPI spectrum of HCl in the excitation region 88,200-88,900 cm^-1 for spectroscopic and dynamic purposes are demonstrated. The mechanism of the three-photon excitation in the I¹Δ₂-X¹∑⁺ transition is discussed.

Original language	English
Pages (from-to)	235-239
Number of pages	5
Journal	Journal of Molecular Structure
Volume	563-564
DOIs	https://doi.org/10.1016/S0022-2860(00)00880-2
Publication status	Published - 28 May 2001

Bibliographical note

Funding Information:
The financial support of the University Research Fund, University of Iceland and the Icelandic Science Foundation is gratefully acknowledged.

Other keywords

Absorption
Hydrogen halides
Lasers
REMPI
Rydberg state

Access to Document

10.1016/S0022-2860(00)00880-2

Cite this

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title = "Three-photon absorption spectroscopy: (3+1)REMPI of HCl (I1Δ2-X1∑+)",

abstract = "Improved spectroscopic parameters for the I1Δ2 Rydberg state and rotational population in the ground state of HCl are derived from simulation analysis of the (3+1)REMPI specrum. The superiority of using the (3+1)REMPI spectrum of HCl in the excitation region 88,200-88,900 cm-1 for spectroscopic and dynamic purposes are demonstrated. The mechanism of the three-photon excitation in the I1Δ2-X1∑+ transition is discussed.",

keywords = "Absorption, Hydrogen halides, Lasers, REMPI, Rydberg state",

author = "H. Wang and A. Kvaran",

note = "Funding Information: The financial support of the University Research Fund, University of Iceland and the Icelandic Science Foundation is gratefully acknowledged.",

year = "2001",

month = may,

day = "28",

doi = "10.1016/S0022-2860(00)00880-2",

language = "English",

volume = "563-564",

pages = "235--239",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

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TY - JOUR

T1 - Three-photon absorption spectroscopy

T2 - (3+1)REMPI of HCl (I1Δ2-X1∑+)

AU - Wang, H.

AU - Kvaran, A.

N1 - Funding Information: The financial support of the University Research Fund, University of Iceland and the Icelandic Science Foundation is gratefully acknowledged.

PY - 2001/5/28

Y1 - 2001/5/28

N2 - Improved spectroscopic parameters for the I1Δ2 Rydberg state and rotational population in the ground state of HCl are derived from simulation analysis of the (3+1)REMPI specrum. The superiority of using the (3+1)REMPI spectrum of HCl in the excitation region 88,200-88,900 cm-1 for spectroscopic and dynamic purposes are demonstrated. The mechanism of the three-photon excitation in the I1Δ2-X1∑+ transition is discussed.

AB - Improved spectroscopic parameters for the I1Δ2 Rydberg state and rotational population in the ground state of HCl are derived from simulation analysis of the (3+1)REMPI specrum. The superiority of using the (3+1)REMPI spectrum of HCl in the excitation region 88,200-88,900 cm-1 for spectroscopic and dynamic purposes are demonstrated. The mechanism of the three-photon excitation in the I1Δ2-X1∑+ transition is discussed.

KW - Absorption

KW - Hydrogen halides

KW - Lasers

KW - REMPI

KW - Rydberg state

UR - http://www.scopus.com/inward/record.url?scp=0035962497&partnerID=8YFLogxK

U2 - 10.1016/S0022-2860(00)00880-2

DO - 10.1016/S0022-2860(00)00880-2

M3 - Article

AN - SCOPUS:0035962497

SN - 0022-2860

VL - 563-564

SP - 235

EP - 239

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -