TY - JOUR
T1 - Resonance enhanced multiphoton ionization of the hydrogen halides
T2 - Rotational structure and anomalies in Rydberg and ion-pair states of HCl and HBr
AU - Kvaran, Ágúst
AU - Wang, Huasheng
AU - Logadóttir, Áshildur
PY - 2000/6/22
Y1 - 2000/6/22
N2 - The studies of (2+1) resonance enhanced multiphoton ionization (REMPI) rotational spectra of HCl and HBr, emphasizing analysis of the rotational energy structures of various vibrational states of the F(1Δ), E(1Σ+), and the V(1Σ+) states are presented. Experimental spectra, recorded at room temperature, are compared with calculated spectra, obtained for unperturbed systems and/or used to derive energies and energy spacings of rotational quantum levels in the excited states. Spectroscopic parameters for the F states are obtained and data are interpreted and analyzed in order to derive both qualitative and quantitative information on state interactions.
AB - The studies of (2+1) resonance enhanced multiphoton ionization (REMPI) rotational spectra of HCl and HBr, emphasizing analysis of the rotational energy structures of various vibrational states of the F(1Δ), E(1Σ+), and the V(1Σ+) states are presented. Experimental spectra, recorded at room temperature, are compared with calculated spectra, obtained for unperturbed systems and/or used to derive energies and energy spacings of rotational quantum levels in the excited states. Spectroscopic parameters for the F states are obtained and data are interpreted and analyzed in order to derive both qualitative and quantitative information on state interactions.
UR - http://www.scopus.com/inward/record.url?scp=0033704641&partnerID=8YFLogxK
U2 - 10.1063/1.481725
DO - 10.1063/1.481725
M3 - Article
AN - SCOPUS:0033704641
SN - 0021-9606
VL - 112
SP - 10811
EP - 10820
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 24
ER -