Relative energy and structural differences of axial and equatorial 1-fluoro-1-silacyclohexane

Laura B. Favero, Biagio Velino, Walther Caminati*, Ingvar Árnason, Ágúst Kvaran

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

The rotational spectra of the main isotopomer, of the 29Si and of all 13C isotopologues of axial and equatorial forms of 1-fluoro-silacyclohexane have been measured by conventional (only main species) and molecular beam Fourier transform microwave spectroscopy. r0 and partial rs structures are given separately for the two forms. The main structural differences are discussed. From dipole moments and relative intensity measurements, a slight preference (EEq - EAx = 42 ± 24 cm-1) for the axial conformer was found. The rotational spectra of some, the most intense, vibrational satellites have also been measured. They belong to the ring-puckering motions.

Original languageEnglish
Pages (from-to)9995-9999
Number of pages5
JournalJournal of Physical Chemistry A
Volume110
Issue number33
DOIs
Publication statusPublished - 24 Aug 2006

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