Dissociative ionization of the potential focused electron beam induced deposition precursor π-allyl ruthenium(II) tricarbonyl bromide, a combined theoretical and experimental study

Maicol Cipriani, Rachel M. Thorman, Christopher R. Brewer, Lisa McElwee-White, Oddur Ingólfsson*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Abstract: Here we present a combined theoretical and experimental study on dissociative ionization of (η3-allyl)Ru(CO)3Br, a potential precursor for focused electron beam induced deposition. Experimental appearance energies are determined by electron impact ionization and relative cross sections for selected fragmentation channels are presented from their respective thresholds to about 70 eV incident electron energy. Threshold energies for individual fragmentation channels are computed at the hybrid density functional and coupled cluster level of theory and compared to the respective experimental appearance energies. Graphical abstract: [Figure not available: see fulltext.].

Original languageEnglish
Article number227
JournalEuropean Physical Journal D
Volume73
Issue number10
DOIs
Publication statusPublished - 1 Oct 2019

Bibliographical note

Publisher Copyright:
© 2019, EDP Sciences / Società Italiana di Fisica / Springer-Verlag GmbH Germany, part of Springer Nature.

Other keywords

  • Atomic Physics

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